Combine all of the brine ingredients and bring to a boil.
Allow to cool completely and add 4 boneless pork chops to brine. Leave in brine for 24 hours.
Remove chops from brine, rinse with cold water and pat dry with paper towels.
Rub chops with rub ingredients.
Brush chops with olive oil and grill over a medium hot grill.
Grill for approx. 5 minutes per side or until a thermometer reads 140 degrees.